Crystal structure of {bis[2-(3,5-dimethylpyrazol-1-yl-κN 2)ethyl]amine-κN}chloridoplatinum(II) chloride dihydrate1
نویسندگان
چکیده
The title complex, [PtCl(C14H23N5)]Cl 2H2O, is isomorphous with the Pd compound characterized previously [Mendoza, Bernès & Mendoza-Dı́az (2006). Acta Cryst. E62, m2934– m2936]. The angle between pyrazole mean planes in the main ligand is 88.3 (4) , similar to that observed in the Pd analogue [87.62 (11) ]. This tridentate ligand adopts a conformation approximating a twofold symmetry, allowing its coordination to the metal atom, together with a chloride ligand, in an almost perfect square-planar geometry. A chloride anion and two water molecules in the asymmetric unit form a hydrogenbonded network connected to the complex molecules in the crystal via the NH amine groups, forming chains along [100].
منابع مشابه
Coordination of bis(pyrazol-1-yl)amine to palladium(II): influence of the co-ligands and counter-ions on the molecular and crystal structures1
The structures of a series of complexes with general formula n[Pd(pza)X]Y·mH2O (n = 1, 2; X = Cl, Br, I, N3, NCS; Y = NO3, I, N3, [Pd(SCN)4]; m = 0, 0.5, 1) have been determined, where pza is the tridentate ligand bis-[2-(3,5-di-methyl-pyrazol-1-yl)eth-yl]amine, C14H23N5. In all complexes, {bis-[2-(3,5-di-methyl-pyrazol-1-yl-κN (2))eth-yl]amine-κN}chlorido-palladium nitrate, [Pd(pza)Cl]NO3, (1)...
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عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015